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Liquids - When a chemical
agent is used for its liquid effect, evaporation causes the agent to
form into a vapor. Depending on volatility, vapor clouds, which tend
to stand near the surface because of high vapor density, are usually
of low concentration and have about the same temperature of the surrounding
air. Furthermore, vapor density governs the extent that the vapor will
mix with air. Persistence agents are those with high vapor density impact
at ground level with very little evaporation of the same, and while
drops are airborne, and after impacting, the liquid continues to evaporate.
The rate at which the liquid will evaporate at a given temperature and
pressure is governed by the agent vapor pressure. Initial concentrations
are lower, since the vapor source is not instantaneous as a vapor agent
is, but evolves over a long period until the liquid source is expended.
Liquid agents may be absorbed, being taken in through the pores of a
surface, and adsorbed, i.e., accumulated on a surface of a solid, and
they may also evaporate. Desorption, i.e., changing from an adsorbed
state to a gaseous state and going back into the air, begins as the
liquid is no more present on the surface. The vapor concentration over
areas contaminated with a liquid agent tends to be less than with newly
formed vapor clouds, and downwind agent concentrations are not nearly
as great as with other types of agents.
Chemical agents [1]
may be grouped according to use as follows:
• Toxic
Chemical agents: capable of producing incapacitation, serious injury,
or death.
Chemical compounds [1]
may be grouped according to use as follows:
• Chocking
agents: chemical agents causing irritation and inflammation
of bronchial tubes and lungs. Their primary physiological action is
limited to the respiratory tract, with injury extending to the deepest
part of the lungs.
•
Nerve agents: chemical agents which, when absorbed
into the body by inhalation, by ingestion, or through the skin, affect
body functions by reacting with an enzyme (cholinesterase) throughout
the body, permitting accumulation of a stimulator (acetylcholine). The
major effects are:
1
- Those on voluntary nervous system; e.g., muscle stimulation with uncoordinated
contractions, followed by fatigue and eventual paralysis.
2
- Those on the parasympathetic nervous system; e.g., pinpointed
pupils; bronchial constriction; nausea, vomiting and diarrhea; secretion
of the glands of the nose, mouth, bronchi, and gastrointestinal system.
3
- Those on the central nervous system; e,g., disturbances in thought,
convulsion, coma, and lethal depression of the vital centers of the
brain.
•
Blood agents: chemical agents which when absorbed into
the body primarily by breathing, affect body functions through action
on an intracellular enzyme called cytochrome oxidase. This stops normal
metabolism in every cell in the body, and thus the cells are unable
to use the oxygen brought to them by the blood. The body tissues are
rapidly damaged by this failure to utilize oxygen.
•
Blister agents: chemical agents that are readily absorbed
by both exterior and interior parts of the body, causing inflammation,
blisters, and general destruction of tissue. The agent vapors, besides
affecting the skin, attack the respiratory tract; the effects are usually
more severe in the upper tract. Eyes are very susceptible to blister
agents.
• Defoliants
and herbicides: plant growth regulators and desiccants, these
agents have a hormonal effect on plant organisms, i.e., forcing unnatural
growth or causing leaves and shoots to die.
[1]
The
list includes only chemical agents or compounds of strictly military
importance.
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